ScienceDaily: Chemistry News

Stitching defects into world’s thinnest semiconductor

Thu, 23 May 2013 11:38:38 EDT

Researchers have grown high-quality crystals of molybdenum disulfide, the world's thinnest semiconductor, and studied how these crystals stitch together at the atomic scale to form continuous sheets, gaining key insights into the optical and electronic properties of this new "wonder" material.

Spheres can form squares

Thu, 23 May 2013 09:31:31 EDT

Everybody who has tried to stack oranges in a box knows that a regular packing of spheres in a flat layer naturally leads to a hexagonal pattern, where each sphere is surrounded by six neighbours in a honeycomb-like fashion. Researchers now report an exception to this rule: when small, micrometer-sized particles are placed on a curved oil-water surface, they arrange in a square pattern, as on a chessboard.

Detecting mirror molecules: New technique reliably tells left-handed from right-handed variant of a compound

Wed, 22 May 2013 13:12:12 EDT

Physicists have developed a novel technique that can detect molecular variants in chemical mixtures -- greatly simplifying a process that is one of the most important, though time-consuming, processes in analytical chemistry.

Carbon capture: Making use of minerals

Wed, 22 May 2013 13:10:10 EDT

Ammonium salts could provide a viable way of removing carbon dioxide from the atmosphere via carbon mineralization, studies suggest.

New technique may open up an era of atomic-scale semiconductor devices

Wed, 22 May 2013 11:20:20 EDT

Researchers have developed a new technique for creating high-quality semiconductor thin films at the atomic scale -- meaning the films are only one atom thick. The technique can be used to create these thin films on a large scale, sufficient to coat wafers that are two inches wide, or larger.

Polymer breakthrough inspired by trees and ancient celtic knots

Wed, 22 May 2013 08:53:53 EDT

A new slow-motion method of controlling the synthesis of polymers, which takes inspiration from both trees and Celtic knots, opens up new possibilities in areas including medical devices, drug delivery, elastics and adhesives.

Unique method creates correct mirror image of molecule

Wed, 22 May 2013 08:52:52 EDT

Many molecules have a right and a left form, just like shoes. In pharmaceuticals, it is important that the correct form of the molecule is used. Researchers have been able to produce the one mirror image by using crystals with special properties. This can have a major impact on the production of pharmaceuticals.

Better understanding of water's freezing behavior at nanoscale

Tue, 21 May 2013 15:24:24 EDT

The results of a new study provide direct computational evidence that nucleation of ice in small droplets is strongly size-dependent, an important conclusion in understanding water's behavior at the nanoscale.

New method for tailoring optical processors

Tue, 21 May 2013 12:16:16 EDT

Physicists and engineers have unveiled a robust new method for arranging metal nanoparticles in geometric patterns that can act as optical processors that transform incoming light signals into output of a different color.

Non-wetting fabric that drains sweat invented

Mon, 20 May 2013 16:36:36 EDT

Waterproof fabrics that whisk away sweat could be the latest application of microfluidic technology developed by bioengineers.

Opening doors to foldable electronics with inkjet-printed graphene

Mon, 20 May 2013 15:42:42 EDT

Imagine a bendable tablet computer or an electronic newspaper that could fold to fit in a pocket. The technology for these devices may not be so far off, thanks to new research.

Nanoantennas improve infrared sensing

Mon, 20 May 2013 14:29:29 EDT

Engineers have used a pattern of nanoantennas to develop a new way of turning infrared light into mechanical action, opening the door to more sensitive infrared cameras and more compact chemical-analysis techniques.

Bacteria use hydrogen, carbon dioxide to produce electricity

Sun, 19 May 2013 19:11:11 EDT

Researchers have engineered a strain of electricity-producing bacteria that can grow using hydrogen gas as its sole electron donor and carbon dioxide as its sole source of carbon.

Kinks and curves at the nanoscale: New research shows 'perfect twin boundaries' are not so perfect

Sun, 19 May 2013 19:04:04 EDT

Since 2004, materials scientists and nanotechnology experts have been excited about a special of arrangement of atoms called a "coherent twin boundary" that can add enormous strength to metals like gold and copper. The CTBs are described as "perfect," appearing like a one-atom-thick plane in models and images. New research shows that these boundaries are not perfect. Even more surprising, the newly discovered kinks and defects appear to be the cause of the CTB's strength.

World's smallest liquid droplets ever made in the lab, experiment suggests

Thu, 16 May 2013 20:06:06 EDT

Physicists may have created the smallest drops of liquid ever made in the lab. That possibility has been raised by the results of a recent experiment at the Large Hadron Collider, the world's largest and most powerful particle collider located at the European Laboratory for Nuclear and Particle Physics (CERN) in Switzerland. Evidence of the minuscule droplets was extracted from the results of colliding protons with lead ions at velocities approaching the speed of light.

Add boron for better batteries

Thu, 16 May 2013 16:17:17 EDT

A graphene-boron compound is theoretically capable of storing double the energy of common graphite anodes used in lithium-ion batteries.

Artificial forest for solar water-splitting: First fully integrated artificial photosynthesis nanosystem

Thu, 16 May 2013 14:26:26 EDT

Researchers have created the first fully integrated artificial photosynthesis nanosystem. While "artificial leaf" is the popular term for such a system, the key to this success was an "artificial forest."

Beautiful 'flowers' self-assemble in a beaker

Thu, 16 May 2013 14:22:22 EDT

With the hand of nature trained on a beaker of chemical fluid, the most delicate flower structures have been formed in a laboratory -- and not at the scale of inches, but microns. These minuscule sculptures, curved and delicate, don't resemble the cubic or jagged forms normally associated with crystals, though that's what they are. Rather, fields of carnations and marigolds seem to bloom from the surface of a submerged glass slide, assembling themselves a molecule at a time.

DNA-guided assembly yields novel ribbon-like nanostructures

Thu, 16 May 2013 12:39:39 EDT

DNA "linker" strands coax nano-sized rods to line up in way unlike any other spontaneous arrangement of rod-shaped objects. The arrangement -- with the rods forming "rungs" on ladder-like ribbons -- could result in the fabrication of new nanostructured materials with desired properties.

New insights into how materials transfer heat could lead to improved electronics

Thu, 16 May 2013 10:56:56 EDT

Researchers have published new insights into how materials transfer heat, which could lead eventually to smaller, more powerful electronic devices.

Carbon in a twirl: The science behind a self-assembled nano-carbon helix

Thu, 16 May 2013 10:55:55 EDT

Nanotechnology draws on the fabrication of nanostructures. Scientists have now succeeded in growing a unique carbon structure at the nanoscale that resembles a tiny twirled mustache. Their method might lead the way to the formation of more complex nano-networks.

Observation of second sound in a quantum gas

Wed, 15 May 2013 13:15:15 EDT

Second sound is a quantum mechanical phenomenon, which has been observed only in superfluid helium. Physicists have now proven the propagation of such a temperature wave in a quantum gas.

Squishy hydrogels may be the ticket for studying biological effects of nanoparticles

Wed, 15 May 2013 12:51:51 EDT

A class of water-loving, jelly-like materials with uses ranges ranging from the mundane, such as superabsorbent diaper liners, to the sophisticated, such as soft contact lenses, could be tapped for a new line of serious work: testing the biological effects of nanoparticles, according to scientists.

Cotton offers a new ecologically friendly way to clean up oil spills

Wed, 15 May 2013 11:38:38 EDT

With the Deepwater Horizon disaster emphasizing the need for better ways of cleaning up oil spills, scientists are reporting that unprocessed, raw cotton may be an ideal, ecologically friendly answer, with an amazing ability to sop up oil.

Friction in the nano-world: Physicists discover a new kind of friction

Wed, 15 May 2013 11:38:38 EDT

Whether in vehicle transmissions, hip replacements, or tiny sensors for triggering airbags: The respective components must slide against each other with minimum friction to prevent loss of energy and material wear. Investigating the friction behavior of nanosystems, scientists have discovered a previously unknown type of friction that sheds new light on some previously unexplainable phenomena.

Obtaining polymers with à la carte optical and electrical properties

Wed, 15 May 2013 08:53:53 EDT

Scientists have created nanostructured composite materials with specific optical and electrical properties that vary according to size. These properties allow researchers to synthesize particles of the size corresponding to the desired properties, and by adding these particles to polymers, to give the final product one specific property or another.

Electronics comes to paper: Paper, being light and foldable, works well for electrically conducting structures

Wed, 15 May 2013 08:52:52 EDT

Paper, being a light and foldable raw material, is a cost-efficient and simple means of generating electrically conducting structures.

New uses for tiny carbon nanotubes: Adding ionic liquid to nanotube films could build smaller gadgets

Tue, 14 May 2013 19:06:06 EDT

Nanotubes are stronger than steel and smaller than any element of silicon-based electronics. They can potentially process information faster while using less energy. The challenge has been figuring out how to incorporate these properties into useful electronic devices. Now scientists have discovered that by adding ionic liquid -- a kind of liquid salt -- they can modify the optical transparency of single-walled carbon nanotube films in a controlled pattern.

Chemists demonstrate nanoscale alloys so bright they could have potential medical applications

Tue, 14 May 2013 12:28:28 EDT

Alloys like bronze and steel have been transformational for centuries, yielding top-of-the-line machines necessary for industry. As scientists move toward nanotechnology, however, the focus has shifted toward creating alloys at the nanometer scale -- producing materials with properties unlike their predecessors. Now, new research demonstrates that nanometer-scale alloys possess the ability to emit light so bright they could have potential applications in medicine.

Engineered biomaterial could improve success of medical implants

Tue, 14 May 2013 12:28:28 EDT

Expensive, state-of-the-art medical devices and surgeries often are thwarted by the body's natural response to attack something in the tissue that appears foreign. Now, engineers have demonstrated in mice a way to prevent this sort of response.

Making gold green: New non-toxic method for mining gold

Tue, 14 May 2013 11:28:28 EDT

Scientists have struck gold in the laboratory. They have discovered an inexpensive and environmentally benign method that uses simple cornstarch -- instead of cyanide -- to isolate gold from raw materials in a selective manner. This green method extracts gold from crude sources and leaves behind other metals that are often found mixed together with the crude gold.

Scientists uncover fundamental property of astatine -- rarest naturally occurring element on Earth

Tue, 14 May 2013 11:27:27 EDT

Scientists have carried out ground-breaking experiments to investigate the atomic structure of astatine (atomic number 85), the rarest naturally occurring element on Earth. Through experiments conducted at the radioactive isotope facility ISOLDE at CERN, scientists have accessed, for the first time, the ionization potential of the astatine atom. The successful measurement fills a long-standing gap in Mendeleev's periodic table, since astatine was the last element present in nature for which this fundamental property was unknown.

Bacterium counteracts 'coffee ring effect'

Tue, 14 May 2013 08:53:53 EDT

Ever notice how a dried coffee stain has a thicker outer rim, while the middle of the stain remains almost unsoiled? This 'coffee ring effect' also occurs in other materials. Researchers have now discovered how to counteract coffee rings with 'surfactants', i.e. soap. The key to the discovery was not a kitchen towel, but a bacterium that counteracts the coffee ring effect at the microscopic level.

Physicists light 'magnetic fire' to reveal energy's path

Mon, 13 May 2013 11:52:52 EDT

Physicists have uncovered how energy is released and dispersed in magnetic materials in a process akin to the spread of forest fires, a finding that has the potential to deepen our understanding of self-sustained chemical reactions.

Molecular basis of strawberry aroma

Mon, 13 May 2013 11:09:09 EDT

You know that summer is here when juicy red strawberries start to appear on the shelves. In Germany, this seasonal fruit has never been more popular: on average 3.5 kilos per head were consumed in 2012 -- a full kilogram more than ten years ago. Scientists decided to find out what gives strawberries their characteristic flavor.

Solar panels as inexpensive as paint?

Mon, 13 May 2013 10:36:36 EDT

Researchers are helping develop a new generation of photovoltaic cells that produce more power and cost less to manufacture than what's available today.

Nano-breakthrough: Solving the case of the herringbone crystal

Sun, 12 May 2013 14:12:12 EDT

Leading nanoscientists created beautiful, tiled patterns with flat nanocrystals, but they were left with a mystery: Why did some sets of crystals arrange themselves in an alternating, herringbone style? To find out, they turned to experts in computer simulation.

Perfectly doped quantum dots yield 'colors to dye for'

Fri, 10 May 2013 12:45:45 EDT

This focuses on an ultra-precise method for doping the tiny semiconductors produces vivid hues.

Flawed diamonds promise sensory perfection: Electron spin extended for incredibly tiny magnetic detectors

Fri, 10 May 2013 10:21:21 EDT

By extending the coherence time of electron states to over half a second, scientists have improved the performance of one of the most potent sensors of magnetic fields on the nanoscale -- a diamond defect no bigger than a pair of atoms called a nitrogen vacancy center. The achievement is important news for nanoscale sensors and quantum computing.

New magnetic graphene may revolutionize electronics

Fri, 10 May 2013 07:55:55 EDT

Researchers have managed to give graphene magnetic properties. The breakthrough opens the door to the development of graphene-based spintronic devices, that is, devices based on the spin or rotation of the electron, and could transform the electronics industry.

Heady mathematics: Describing popping bubbles in a foam

Thu, 09 May 2013 14:21:21 EDT

Two applied mathematicians have found a way to mathematically describe the evolution and disappearance of a foam. Using these equations, they were able to generate a movie that shows the complex draining, popping and rearrangement of these bubbles as the foam vanishes.

New advance in biofuel production

Thu, 09 May 2013 12:37:37 EDT

Researchers have developed an enzyme-free ionic liquid pretreatment of cellulosic biomass that makes it easier to recover fermentable sugars for biofuels and to recycle the ionic liquid.

Scientists demonstrate pear shaped atomic nuclei

Thu, 09 May 2013 10:43:43 EDT

Scientists have shown that some atomic nuclei can assume the shape of a pear which contributes to our understanding of nuclear structure and the underlying fundamental interactions.

Device for portable, ultra-precise clocks and quantum sensors developed

Thu, 09 May 2013 09:08:08 EDT

Researchers have developed a portable way to produce ultracold atoms for quantum technology and quantum information processing.

Researchers find a way to make steel without greenhouse-gas emissions

Wed, 08 May 2013 13:31:31 EDT

Steelmaking, a major emitter of climate-altering gases, could be transformed by a new process.

Graphene quantum dots may someday tell if it will rain on Mars

Wed, 08 May 2013 13:18:18 EDT

Chemical engineers may be able to improve humidity and pressure sensors, particularly those used in outer space.

Engineers fine-tune the sensitivity of nano-chemical sensor

Wed, 08 May 2013 12:28:28 EDT

Researchers have discovered a technique for controlling the sensitivity of graphene chemical sensors.

'Invisibility cloak' for thermal flow constructed

Wed, 08 May 2013 09:29:29 EDT

By means of special metamaterials, light and sound can be passed around objects. Researchers have now succeeded in demonstrating that the same materials can also be used to specifically influence the propagation of heat. A structured plate of copper and silicon conducts heat around a central area without the edge being affected.

Elucidating energy shifts in optical tweezers

Wed, 08 May 2013 09:29:29 EDT

Physicists are providing an all-in-one guide to help calculate the effect the use of optical tweezers has on the energy levels of atoms under study. A small piece of paper sticks to an electrically charged plastic ruler. The principle of this simple classroom physics experiment is applied at the microscopic scale by so-called optical tweezers to get the likes of polystyrene micro-beads and even living cells to "stick" to a laser beam, or to trap atoms at ultra-low temperatures.

20-million-year-old amber shatters theories of glass as a liquid

Tue, 07 May 2013 15:49:49 EDT

Fact or fiction? Stained glass found in medieval cathedrals becomes thicker at the bottom because glass moves over time. For years researchers have had their doubts, now scientists have further evidence that glass is not going anywhere.

New mechanism converts natural gas to energy faster, captures carbon dioxide

Tue, 07 May 2013 12:48:48 EDT

Chemical engineering researchers have identified a new mechanism to convert natural gas into energy up to 70 times faster, while effectively capturing the greenhouse gas carbon dioxide.

Cleaner, low temperature nuclear fuels?

Tue, 07 May 2013 11:55:55 EDT

The search for cleaner, low temperature nuclear fuels has produced a surprising result for a team of experts. First they created a stable version of a 'trophy molecule' that has eluded scientists for decades. Now they have discovered that the bonding within this molecule is far different than expected. Remarkably their findings have shown that it behaves in much the same way as its counterparts in the well-known transitional metals such as chromium, molybdenum and tungsten.

New technique to track cell interactions in living bodies developed

Mon, 06 May 2013 18:16:16 EDT

Researchers have developed a new technique to see how different types of cells interact in a living mouse.

New device can extract human DNA with full genetic data in minutes

Mon, 06 May 2013 13:21:21 EDT

Engineers have created a device that can extract human DNA from fluid samples in a simpler, more efficient and environmentally friendly way than conventional methods.

Unique method for creating uniform nanoparticles developed

Mon, 06 May 2013 11:40:40 EDT

Researchers have developed unique approach for the synthesis of highly uniform icosahedral nanoparticles made of platinum. Results showed that the key factors for the shape control include fast nucleation, kinetically controlled growth, and protection from oxidation by air.

Engineers manipulate a buckyball by inserting a single water molecule

Mon, 06 May 2013 10:33:33 EDT

Engineering researchers have developed a technique to isolate a single water molecule inside a buckyball and drive motion of the "big" nonpolar ball through the encapsulated "small" polar H2O molecule, a controlling transport mechanism in a nanochannel under an external electric field. This method could lead to new applications including effective ways to control drug delivery and to assemble C60-based functional 3D structures at the nanoscale level.

Invisible pattern can put a stop to counterfeit designer clothing

Mon, 06 May 2013 09:51:51 EDT

There is now a way to differentiate between designer clothing and knockoffs. Researchers have produced a thread with unique optical properties, which can be used to create invisible patterns in fabrics that are only visible under polarized light.

Microwave oven cooks up solar cell material

Mon, 06 May 2013 09:49:49 EDT

Metallurgists used an old microwave oven to produce a nanocrystal semiconductor rapidly using cheap, abundant and less toxic metals than other semiconductors. They hope it will be used for more efficient photovoltaic solar cells and LED lights, biological sensors and systems to convert waste heat to electricity.

Improving materials that convert heat to electricity and vice-versa: Turning waste heat into electricity

Sun, 05 May 2013 14:59:59 EDT

Thermoelectric materials can be used to turn waste heat into electricity or to provide refrigeration without any liquid coolants, and new study has found a way to nearly double the efficiency of a particular class of them that's made with organic semiconductors.

'Going negative' pays for nanotubes

Fri, 03 May 2013 11:47:47 EDT

Researchers turn carbon nanotubes into negatively charged liquid crystals that could enhance the creation of fibers and films.